Velpula Gangamallaiah, Takeda Takashi, Adisoejoso Jinne, Inukai Koji, Tahara Kazukuni, Mali Kunal S, Tobe Yoshito, De Feyter Steven
Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven-University of Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium.
Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan.
Chem Commun (Camb). 2017 Jan 17;53(6):1108-1111. doi: 10.1039/c6cc09188a.
We report on the design and fabrication of a four-component supramolecular network using the 'core-shell' approach. Each 'core' component templates the formation of an outer 'shell' leading to formation of three concentric 'shells' around the central guest. The 'shells' are formed only in presence of guests thus demonstrating remarkable selectivity in molecular recognition.
我们报道了一种采用“核壳”方法设计和制备的四组分超分子网络。每个“核”组分作为模板引导外部“壳”的形成,从而在中心客体周围形成三个同心“壳”。“壳”仅在客体存在时形成,因此在分子识别中表现出显著的选择性。