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2-硝基苯胺的催化还原:综述。

Catalytic reduction of 2-nitroaniline: a review.

机构信息

Institute of Chemistry, University of the Punjab, New Campus Lahore, Lahore, 54590, Pakistan.

Center for Undergraduate Studies, University of the Punjab, New Campus Lahore, Lahore, 54590, Pakistan.

出版信息

Environ Sci Pollut Res Int. 2017 Mar;24(7):6446-6460. doi: 10.1007/s11356-016-8317-2. Epub 2017 Jan 4.

DOI:10.1007/s11356-016-8317-2
PMID:28054271
Abstract

2-nitroaniline (2-NA) is highly toxic and environmental contaminant. It is reduced to less toxic and environmental benign product o-phenylenediamine by using different reducing agents like sodium borohydride, potassium borohydride, or hydrazine hydrate in the presence of various catalytic systems. These catalytic systems have various advantages and drawbacks. Silica-supported gold nanoparticles are frequently reported catalyst for the reduction of 2-nitroaniline in aqueous medium. In this review article, different catalytic systems reported for reduction of o-nitroaniline under various reaction conditions have been discussed. The critical review of the recent research progress for development of novel catalysts used for the reduction of 2-nitroaniline has been provided here.

摘要

2-硝基苯胺(2-NA)是一种剧毒且对环境有污染的物质。在不同的催化体系中,使用不同的还原剂,如硼氢化钠、硼氢化钾或水合肼,可以将其还原为毒性较小且环境友好的邻苯二胺。这些催化体系各有优缺点。负载型金纳米粒子是一种常用于在水相介质中还原 2-硝基苯胺的催化剂。本文综述了不同催化体系在不同反应条件下还原邻硝基苯胺的报道,并对新型催化剂在还原 2-硝基苯胺方面的研究进展进行了评述。

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