Cherny Alexander Yu, Anitas Eugen M, Osipov Vladimir A, Kuklin Alexander I
Joint Institute for Nuclear Research, Dubna 141980, Russian Federation.
Phys Chem Chem Phys. 2017 Jan 18;19(3):2261-2268. doi: 10.1039/c6cp07496k.
The small-angle scattering (SAS) from the Cantor surface fractal on the plane and Koch snowflake is considered. We develop the construction algorithm for the Koch snowflake, which makes possible the recurrence relation for the scattering amplitude. The surface fractals can be decomposed into a sum of surface mass fractals for arbitrary fractal iteration, which enables various approximations for the scattering intensity. It is shown that for the Cantor fractal, one can neglect with good accuracy the correlations between the mass fractal amplitudes, while for the Koch snowflake, these correlations are important. It is shown that nevertheless, correlations can be built in the mass fractal amplitudes, which explains the decay of the scattering intensity I(q) ∼ q, with 1 < D < 2 being the fractal dimension of the perimeter. The curve I(q)q is found to be log-periodic in the fractal region with a period equal to the scaling factor of the fractal. The log-periodicity arises from the self-similarity of the sizes of basic structural units rather than from correlations between their distances. A recurrence relation is obtained for the radius of gyration of the Koch snowflake, which is solved in the limit of infinite iterations. The present analysis allows us to obtain additional information from SAS data, such as the edges of the fractal regions, the fractal iteration number and the scaling factor.
研究了平面上康托表面分形和科赫雪花的小角散射(SAS)。我们开发了科赫雪花的构造算法,这使得散射振幅的递推关系成为可能。对于任意分形迭代,表面分形可以分解为表面质量分形的和,这使得对散射强度有各种近似。结果表明,对于康托分形,可以很好地忽略质量分形振幅之间的相关性,而对于科赫雪花,这些相关性很重要。结果表明,尽管如此,可以在质量分形振幅中建立相关性,这解释了散射强度I(q) ∼ q的衰减,其中1 < D < 2是周长的分形维数。发现曲线I(q)q在分形区域是对数周期的,周期等于分形的标度因子。对数周期性源于基本结构单元大小的自相似性,而不是它们之间距离的相关性。得到了科赫雪花回转半径的递推关系,并在无限迭代的极限情况下求解。目前的分析使我们能够从SAS数据中获得额外信息,如分形区域的边缘、分形迭代次数和标度因子。