• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过侧链工程策略继承 TADF 小分子的特性，使聚合物具有高达 74%的 PLQY 和超过 16%的外量子效率的蓝绿光发射。

Inheriting the Characteristics of TADF Small Molecule by Side-Chain Engineering Strategy to Enable Bluish-Green Polymers with High PLQYs up to 74% and External Quantum Efficiency over 16% in Light-Emitting Diodes.

机构信息

Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan, 430072, P. R. China.

出版信息

Adv Mater. 2017 Mar;29(11). doi: 10.1002/adma.201604223. Epub 2017 Jan 6.

DOI:10.1002/adma.201604223
PMID:28060416
Abstract

Thermally activated delayed fluorescence (TADF) polymers are designed and synthesized by grafting the TADF emitter to the side chain of the polycarbazole backbone. By employing these TADF polymers with large ratio of delayed fluorescence component and high photoluminescence quantum yield as the emitters, the solution-processed light-emitting diodes achieve a maximal external quantum efficiency of 16.1% at a luminance of around 100 cd m .

摘要

热致延迟荧光（TADF）聚合物是通过将 TADF 发射器接枝到聚咔唑主链的侧链上来设计和合成的。通过将具有大延迟荧光成分比例和高光致发光量子产率的这些 TADF 聚合物用作发射器，溶液处理的发光二极管在约 100 cd m 的亮度下实现了最大外量子效率 16.1%。

相似文献

1
Inheriting the Characteristics of TADF Small Molecule by Side-Chain Engineering Strategy to Enable Bluish-Green Polymers with High PLQYs up to 74% and External Quantum Efficiency over 16% in Light-Emitting Diodes.通过侧链工程策略继承 TADF 小分子的特性，使聚合物具有高达 74%的 PLQY 和超过 16%的外量子效率的蓝绿光发射。
Adv Mater. 2017 Mar;29(11). doi: 10.1002/adma.201604223. Epub 2017 Jan 6.
2
Highly Efficient Solution-Processed Thermally Activated Delayed Fluorescence Bluish-Green and Hybrid White Organic Light-Emitting Diodes Using Novel Bipolar Host Materials.使用新型双极主体材料制备高效溶液处理热激活延迟荧光蓝绿光和混合白光有机发光二极管。
ACS Appl Mater Interfaces. 2019 Dec 11;11(49):45939-45948. doi: 10.1021/acsami.9b14168. Epub 2019 Dec 2.
3
Enhanced Upconversion of Triplet Excitons for Conjugated Polymeric Thermally Activated Delayed Fluorescence Emitters by Employing an Intramolecular Sensitization Strategy.通过采用分子内敏化策略增强共轭聚合物热激活延迟荧光发射体中三线态激子的上转换
ACS Appl Mater Interfaces. 2021 Feb 24;13(7):8997-9005. doi: 10.1021/acsami.0c22494. Epub 2021 Feb 11.
4
Coumarin-Based Thermally Activated Delayed Fluorescence Emitters with High External Quantum Efficiency and Low Efficiency Roll-off in the Devices.基于香豆素的热激活延迟荧光发射器，具有高效率和低效率滚降的器件。
ACS Appl Mater Interfaces. 2017 Mar 15;9(10):8848-8854. doi: 10.1021/acsami.6b15816. Epub 2017 Mar 2.
5
Efficient and Stable Organic Light-Emitting Diodes Employing Indolo[2,3-]indole-Based Thermally Activated Delayed Fluorescence Emitters.采用基于吲哚并[2,3-]吲哚的热激活延迟荧光发射体的高效且稳定的有机发光二极管。
ACS Appl Mater Interfaces. 2020 Feb 5;12(5):6127-6136. doi: 10.1021/acsami.9b19474. Epub 2020 Jan 22.
6
Highly Efficient All-Solution-Processed Fluorescent Organic Light-Emitting Diodes Based on a Novel Self-Host Thermally Activated Delayed Fluorescence Emitter.基于新型自主体热激活延迟荧光发射器的高效全溶液处理荧光有机发光二极管。
ACS Appl Mater Interfaces. 2017 Jul 5;9(26):21900-21908. doi: 10.1021/acsami.7b04146. Epub 2017 Jun 22.
7
Chiral TADF-Active Polymers for High-Efficiency Circularly Polarized Organic Light-Emitting Diodes.用于高效圆偏振有机发光二极管的手性热活化延迟荧光活性聚合物
Angew Chem Int Ed Engl. 2021 Oct 25;60(44):23619-23624. doi: 10.1002/anie.202110794. Epub 2021 Sep 29.
8
Thermally Activated Delayed Fluorescence Polymers for Efficient Solution-Processed Organic Light-Emitting Diodes.用于高效溶液处理有机发光二极管的热激活延迟荧光聚合物。
Adv Mater. 2016 Jun;28(21):4019-24. doi: 10.1002/adma.201505026. Epub 2016 Mar 22.
9
Triazine-Acceptor-Based Green Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes.用于有机发光二极管的基于三嗪受体的绿色热激活延迟荧光材料
Materials (Basel). 2019 Aug 20;12(16):2646. doi: 10.3390/ma12162646.
10
Creating a thermally activated delayed fluorescence channel in a single polymer system to enhance exciton utilization efficiency for bluish-green electroluminescence.在单一聚合物体系中创建热激活延迟荧光通道以提高用于蓝绿色电致发光的激子利用效率。
Chem Commun (Camb). 2016 Feb 7;52(11):2292-5. doi: 10.1039/c5cc09797e.

引用本文的文献

1
The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation.热激活延迟荧光材料的黄金时代：设计与开发
Chem Rev. 2024 Dec 25;124(24):13736-14110. doi: 10.1021/acs.chemrev.3c00755. Epub 2024 Dec 12.
2
Acceptor Copolymerized Axially Chiral Conjugated Polymers with TADF Properties for Efficient Circularly Polarized Electroluminescence.具有热激活延迟荧光特性的受体共聚轴向手性共轭聚合物用于高效圆偏振电致发光
Adv Sci (Weinh). 2024 Jun;11(23):e2309031. doi: 10.1002/advs.202309031. Epub 2024 Mar 29.
3
New Light-Green Thermally Activated Delayed Fluorescence Polymer Based on Dimethylacridine-Triphenyltriazine Light-Emitting Unit and Tetraphenylsilane Moiety as Non-Conjugated Backbone.
基于二甲基吖啶-三苯基三嗪发光单元和四苯基硅烷部分作为非共轭主链的新型浅绿色热激活延迟荧光聚合物。
Polymers (Basel). 2022 Dec 24;15(1):67. doi: 10.3390/polym15010067.
4
Fused tetracyclic tris[1,2,4]triazolo[1,3,5]triazine as a novel rigid electron acceptor for efficient thermally activated delayed fluorescence emitters.稠合四环三[1,2,4]三唑并[1,3,5]三嗪作为一种新型刚性电子受体用于高效热激活延迟荧光发光体。
RSC Adv. 2020 Apr 20;10(26):15523-15529. doi: 10.1039/d0ra01925a. eCollection 2020 Apr 16.
5
Weaving host matrices with intermolecular hydrogen bonds for high-efficiency white thermally activated delayed fluorescence.通过分子间氢键编织主体基质以实现高效白色热激活延迟荧光
Chem Sci. 2021 Oct 12;12(43):14519-14530. doi: 10.1039/d1sc04188f. eCollection 2021 Nov 10.
6
Hyperfluorescent polymers enabled by through-space charge transfer polystyrene sensitizers for high-efficiency and full-color electroluminescence.通过空间电荷转移聚苯乙烯敏化剂实现的用于高效全彩电致发光的超荧光聚合物。
Chem Sci. 2021 Sep 3;12(39):13083-13091. doi: 10.1039/d1sc04389g. eCollection 2021 Oct 13.
7
Phenoxazine-Dibenzothiophene Sulfoximine Emitters Featuring Both Thermally Activated Delayed Fluorescence and Aggregation Induced Emission.兼具热活化延迟荧光和聚集诱导发光特性的吩恶嗪-二苯并噻吩亚砜亚胺发光体
Molecules. 2021 Aug 29;26(17):5243. doi: 10.3390/molecules26175243.
8
Using fluorene to lock electronically active moieties in thermally activated delayed fluorescence emitters for high-performance non-doped organic light-emitting diodes with suppressed roll-off.利用芴将电子活性部分锁定在热激活延迟荧光发射体中，用于具有抑制滚降特性的高性能非掺杂有机发光二极管。
Chem Sci. 2020 Nov 26;12(4):1495-1502. doi: 10.1039/d0sc05631f.
9
Recent Advances in Thermally Activated Delayed Fluorescent Polymer-Molecular Designing Strategies.热激活延迟荧光聚合物分子设计策略的最新进展
Front Chem. 2020 Aug 14;8:725. doi: 10.3389/fchem.2020.00725. eCollection 2020.
10
Efficient Aggregation-Induced Delayed Fluorescence Luminogens for Solution-Processed OLEDs With Small Efficiency Roll-Off.用于溶液处理的效率滚降小的有机发光二极管的高效聚集诱导延迟荧光发光体。
Front Chem. 2020 Apr 7;8:193. doi: 10.3389/fchem.2020.00193. eCollection 2020.