Houston T E, Poore M W
a Monitoring and Laboratory Division, Air Resources Board, California Environmental Protection Agency , Sacramento , California , USA.
J Air Waste Manag Assoc. 1996 Oct;46(10):990-992. doi: 10.1080/10473289.1996.10467535.
The direct Karl Fischer (KF) titration method has known interferences for measuring water content. In addition, in analyzing some paints, KF can fail to produce an accurate analysis. The California Air Resources Board (GARB) staff has developed a KF procedure that can be used to determine the water content of consumer products. The procedure uses an oven accessory to the titration system, and is based on a distillation method developed by the California Polytechnical University at San Luis Obispo (Cal Poly). Samples are diluted in l-methoxy-2-propanol (MPA), and an aliquot is injected into an enclosed oven system, where the MPA/water azeotrope is swept directly into the KF titration vessel. The technique is accurate and precise and, thus far, proves to be a fast and reliable method for analysis.
