Liang Zhijie, Wang Ke, Zhang Dongdi, Ma Pengtao, Niu Jingyang, Wang Jingping
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China.
Dalton Trans. 2017 Jan 31;46(5):1368-1371. doi: 10.1039/c6dt04223f.
A new heteropolyniobate, [FeNbO], persists in aqueous solution by means of electrospray ionization mass spectrometry. It has been synthesized and characterized by IR, TGA, EDX-SEM, magnetic and single-crystal X-ray diffraction, and it features an Fe-centred Nb-Keggin unit {FeNb}.