Suzuki Shin, Yamaguchi Junichiro
Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Chem Commun (Camb). 2017 Feb 4;53(10):1568-1582. doi: 10.1039/c6cc09550j. Epub 2017 Jan 10.
Multiply arylated arenes are privileged structures with highly useful functions and fascinating optoelectronic and biological properties. This feature article reports the synthesis of fully arylated (hetero)arenes bearing more than two different aryl substituents and categorizes this emerging topic by the type of (hetero)arene core and the type of chemistry employed to install the (hetero)aryl substituents.
多芳基化芳烃是具有高度有用功能以及迷人的光电和生物学特性的优势结构。这篇专题文章报道了带有两种以上不同芳基取代基的全芳基化(杂)芳烃的合成,并根据(杂)芳烃核心类型和用于安装(杂)芳基取代基的化学类型对这个新兴主题进行了分类。