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碳质球粒陨石:恒星与生命之间潜在演化路径的编年史。

Carbonaceous Chondrite Meteorites: the Chronicle of a Potential Evolutionary Path between Stars and Life.

作者信息

Pizzarello Sandra, Shock Everett

机构信息

School of Molecular Sciences, Arizona State University, Tempe, AZ, 85287-1604, USA.

School of Earth & Space Exploration, Arizona State University, Tempe, AZ, 85218, USA.

出版信息

Orig Life Evol Biosph. 2017 Sep;47(3):249-260. doi: 10.1007/s11084-016-9530-1. Epub 2017 Jan 11.

DOI:10.1007/s11084-016-9530-1
PMID:28078499
Abstract

The biogenic elements, H, C, N, O, P and S, have a long cosmic history, whose evolution can still be observed in diverse locales of the known universe, from interstellar clouds of gas and dust, to pre-stellar cores, nebulas, protoplanetary discs, planets and planetesimals. The best analytical window into this cosmochemical evolution as it neared Earth has been provided so far by the small bodies of the Solar System, some of which were not significantly altered by the high gravitational pressures and temperatures that accompanied the formation of larger planets and may carry a pristine record of early nebular chemistry. Asteroids have delivered such records, as their fragments reach the Earth frequently and become available for laboratory analyses. The Carbonaceous Chondrite meteorites (CC) are a group of such fragments with the further distinction of containing abundant organic materials with structures as diverse as kerogen-like macromolecules and simpler compounds with identical counterparts in Earth's biosphere. All have revealed a lineage to cosmochemical synthetic regimes. Several CC show that asteroids underwent aqueous alteration of their minerals or rock metamorphism but may yet yield clues to the reactivity of organic compounds during parent-body processes, on asteroids as well as larger ocean worlds and planets. Whether the exogenous delivery by meteorites held an advantage in Earth's molecular evolution remains an open question as many others regarding the origins of life are. Nonetheless, the natural samples of meteorites allow exploring the physical and chemical processes that might have led to a selected chemical pool amenable to the onset of life. Graphical Abstract ᅟ.

摘要

生物成因元素氢(H)、碳(C)、氮(N)、氧(O)、磷(P)和硫(S)有着漫长的宇宙历史,其演化过程在已知宇宙的不同区域仍可观测到,从气体和尘埃的星际云,到恒星前身核心、星云、原行星盘、行星和小行星。到目前为止,太阳系中的小天体为我们提供了观察这种接近地球时的宇宙化学演化的最佳分析窗口,其中一些小天体并未因伴随大行星形成的高引力压力和温度而发生显著改变,可能保留着早期星云化学的原始记录。小行星就带来了这样的记录,因为它们的碎片经常抵达地球,可供实验室分析。碳质球粒陨石就是这类碎片,其特别之处在于含有丰富的有机物质,这些有机物质的结构多种多样,从类干酪根大分子到与地球生物圈中相同的更简单化合物。所有这些都揭示了与宇宙化学合成机制的联系。一些碳质球粒陨石表明小行星经历了其矿物的水蚀变或岩石变质作用,但仍可能为小行星以及更大的海洋世界和行星上母体过程中有机化合物的反应活性提供线索。陨石的外源输送在地球分子演化中是否具有优势,如同许多其他关于生命起源的问题一样,仍是一个悬而未决的问题。尽管如此,陨石的天然样本使我们能够探索可能导致适合生命起源的特定化学库的物理和化学过程。图形摘要ᅟ

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