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基于织物的碱性直接甲酸盐微流控燃料电池。

Fabric-based alkaline direct formate microfluidic fuel cells.

作者信息

Domalaon Kryls, Tang Catherine, Mendez Alex, Bernal Franky, Purohit Krutarth, Pham Linda, Haan John, Gomez Frank A

机构信息

Department of Chemistry and Biochemistry, California State University, Los Angeles, CA, USA.

Department of Chemistry and Biochemistry, California State University, Fullerton, CA, USA.

出版信息

Electrophoresis. 2017 Apr;38(8):1224-1231. doi: 10.1002/elps.201600306. Epub 2017 Feb 10.

Abstract

Fabric-based microfluidic fuel cells (MFCs) serve as a novel, cost-efficient alternative to traditional FCs and batteries, since fluids naturally travel across fabric via capillary action, eliminating the need for an external pump and lowering production and operation costs. Building on previous research with Y-shaped paper-based MFCs, fabric-based MFCs mitigate fragility and durability issues caused by long periods of fuel immersion. In this study, we describe a microfluidic fabric-based direct formate fuel cell, with 5 M potassium formate and 30% hydrogen peroxide as the anode fuel and cathode oxidant, respectively. Using a two-strip, stacked design, the optimized parameters include the type of encasement, the barrier, and the fabric type. Surface contact of the fabric and laminate sheet expedited flow and respective chemical reactions. The maximum current (22.83 mA/cm ) and power (4.40 mW/cm ) densities achieved with a 65% cotton/35% polyester blend material are a respective 8.7% and 32% higher than previous studies with Y-shaped paper-based MFCs. In series configuration, the MFCs generate sufficient energy to power a handheld calculator, a thermometer, and a spectrum of light-emitting diodes.

摘要

基于织物的微流控燃料电池(MFC)是传统燃料电池和电池的一种新型、经济高效的替代方案,因为流体通过毛细作用自然地在织物中流动,无需外部泵,从而降低了生产和运营成本。基于先前对Y形纸质MFC的研究,基于织物的MFC减轻了长时间燃料浸泡导致的易碎性和耐久性问题。在本研究中,我们描述了一种基于微流控织物的直接甲酸盐燃料电池,分别以5M甲酸钾和30%过氧化氢作为阳极燃料和阴极氧化剂。采用双条堆叠设计,优化参数包括封装类型、屏障和织物类型。织物与层压板的表面接触加快了流动和各自的化学反应。使用65%棉/35%聚酯混合材料实现的最大电流(22.83 mA/cm)和功率(4.40 mW/cm)密度分别比先前对Y形纸质MFC的研究高8.7%和32%。在串联配置中,MFC产生的能量足以驱动手持计算器、温度计和一系列发光二极管。

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