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-聚[[双(-乙酰硫代吗啉-κ)铜(I)]-μ-碘化物]的晶体结构

Crystal structure of -poly[[bis-(-acethyl-thio-morpholine-κ)copper(I)]-μ-iodido].

作者信息

Chiang Hojae, Kim Tae Ho, Park Hyunjin, Kim Jineun

机构信息

Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Jan 1;73(Pt 1):53-55. doi: 10.1107/S2056989016019794.

DOI:10.1107/S2056989016019794
PMID:28083135
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5209771/
Abstract

The reaction of copper(I) iodide with -acetyl-thio-morpholine (, CHNOS) in aceto-nitrile results in a coordination polymer with composition [CuI()] . The Cu atom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between the chains lead to a three-dimensional network.

摘要

碘化亚铜与β-乙酰硫代吗啉（C5H9NOS）在乙腈中的反应生成了一种组成为[CuI(C5H9NOS)]n的配位聚合物。铜原子由两个硫原子和两个碘原子配位，形成扭曲的四面体环境。碘原子的μ-桥连模式导致形成平行于[010]方向延伸的链。链之间的C-H⋯O氢键相互作用形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/1b6791b1954a/e-73-00053-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/fa9afcb29f7f/e-73-00053-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/3aae33b19c5a/e-73-00053-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/1b6791b1954a/e-73-00053-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/fa9afcb29f7f/e-73-00053-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/3aae33b19c5a/e-73-00053-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f8a/5209771/1b6791b1954a/e-73-00053-fig3.jpg

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本文引用的文献

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Reactivity of CuI and CuBr toward Et2S: a reinvestigation on the self-assembly of luminescent copper(I) coordination polymers.
碘化亚铜和溴化亚铜与乙硫醚的反应：对发光铜（I）配位聚合物自组装的再研究。
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