Kondinski Aleksandar, Monakhov Kirill Yu
Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Chemistry. 2017 Jun 12;23(33):7841-7852. doi: 10.1002/chem.201605876. Epub 2017 Feb 20.
This Concept article provides insights into the molecular design and construction aspects of polyoxocuprates (POCus), an emerging class of polyoxometalate (POM)-like architectures featuring low-to-high nuclearity copper(II)-oxo/hydroxo skeletons. POCus have been identified to adopt the structural principles of classical POMs consisting of early transition metals. Their potential to afford motifs of the noble-metal-based POMs is exploited. "Cross-structural topological transformation" is introduced to generalize skeletal relationships between POCus and POMs. The study opens up strategies toward the brand-new structural chemistry of POCus with relevance to homogeneous photocatalysis, medicinal chemistry, molecular magnetism, and quantum computing.
这篇概念文章深入探讨了聚氧铜酸盐（POCus）的分子设计和构建方面，POCus是一类新兴的类似多金属氧酸盐（POM）的结构，具有低核至高核的铜（II）-氧/羟基骨架。已确定POCus采用由早期过渡金属组成的经典POMs的结构原理。利用了它们提供基于贵金属的POMs基序的潜力。引入了“跨结构拓扑转变”来概括POCus和POMs之间的骨架关系。该研究为与均相光催化、药物化学、分子磁学和量子计算相关的POCus全新结构化学开辟了策略。
