由碘代硼二吡咯和抗坏血酸钠促进的光催化全反式维甲酸反应。
Photocatalytic ATRA reaction promoted by iodo-Bodipy and sodium ascorbate.
作者信息
Magagnano G, Gualandi A, Marchini M, Mengozzi L, Ceroni P, Cozzi P G
机构信息
Dipartimento di Chimica "G. Ciamician" ALMA MATER STUDIORUM, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy.
出版信息
Chem Commun (Camb). 2017 Feb 4;53(10):1591-1594. doi: 10.1039/c6cc09387f. Epub 2017 Jan 13.
PMID:28085164
Abstract
Using ascorbate as a sacrificial reductant, iodo-Bodipy dye 1b is able to promote the ATRA reaction between bromoderivatives and alkenes. This finding expands the possibility of using Bodipy dyes to promote photocatalytic reactions in efficient ways.
摘要
使用抗坏血酸盐作为牺牲性还原剂，碘代硼二吡咯染料1b能够促进溴代衍生物与烯烃之间的全反式维甲酸（ATRA）反应。这一发现扩展了以有效方式使用硼二吡咯染料促进光催化反应的可能性。
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