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红外光谱分析掺入乳木果油工业废果壳后的粘土砖。

Infrared analysis of clay bricks incorporated with spent shea waste from the shea butter industry.

机构信息

Department of Physics, Faculty of Science, Annamalai University, Annamalai Nagar, 608002, Chidambaram, Tamilnadu, India.

Department of Physics, Faculty of Science, Annamalai University, Annamalai Nagar, 608002, Chidambaram, Tamilnadu, India.

出版信息

J Environ Manage. 2017 Apr 15;191:66-74. doi: 10.1016/j.jenvman.2017.01.006. Epub 2017 Jan 11.

Abstract

The peculiar challenge of effective disposing abundant spent shea waste and the excellent compositional variation tolerance of clay material offered an impetus to examine the incorporation of spent shea waste into clay material as an eco-friendly disposal route in making clay bricks. For this purpose, the chemical constituent, mineralogical compositions and thermal behavior of both clay material and spent shea waste were initially characterized from which modelled brick specimens incorporating 5-20 wt% of the waste into the clay material were prepared. The clay material showed high proportions of SiO (52.97 wt%) and AlO (27.10 wt%) indicating their rich kaolinitic content: whereas, the inert nature of spent shea waste was exhibited by their low oxide content. The striking similarities in infrared absorption bands of pristine clay material and clay materials incorporated with 15 wt% of spent shea waste showed that the waste incorporation had no impact on bond formation of the clay bricks. Potential performance benefits of developing bricks from clay material incorporated with spent shea waste included improved fluxing agents, economic sintering and making of sustainable bricks. Consequently, the analytical results authenticate the incorporation of spent shea waste into clay materials for various desired benefits aside being an environmental correct route of its disposal.

摘要

有效处理大量废弃乳木果渣的特殊挑战,以及粘土材料出色的组成变化容忍度,促使我们研究将废弃乳木果渣纳入粘土材料中,作为制造粘土砖的环保处理途径。为此,我们首先对粘土材料和废弃乳木果渣的化学成分、矿物成分和热行为进行了表征,然后用粘土材料制备了掺入 5-20wt%废土的模型砖样本。粘土材料中 SiO(52.97wt%)和 AlO(27.10wt%)的比例很高,表明其富含高岭土;而废弃乳木果渣的惰性则表现在其氧化物含量低。原始粘土材料和掺入 15wt%废土的粘土材料的红外吸收带非常相似,表明废土的掺入对粘土砖的键合形成没有影响。从掺入废土的粘土材料中开发砖的潜在性能优势包括改善助熔剂、经济烧结和制造可持续砖。因此,分析结果证明了将废土纳入粘土材料除了是其处理的正确环保途径外,还可以获得各种所需的益处。

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