观察到一种以金属为中心的B-Ta@B管状分子转子和一个具有二十个配位原子的创纪录配位数的完美Ta@B硼鼓。
Observation of a metal-centered B-Ta@B tubular molecular rotor and a perfect Ta@B boron drum with the record coordination number of twenty.
作者信息
Li Wan-Lu, Jian Tian, Chen Xin, Li Hai-Ru, Chen Teng-Teng, Luo Xue-Mei, Li Si-Dian, Li Jun, Wang Lai-Sheng
机构信息
Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Tsinghua University, Beijing 100084, China.
出版信息
Chem Commun (Camb). 2017 Feb 4;53(10):1587-1590. doi: 10.1039/c6cc09570d. Epub 2017 Jan 17.
PMID:28093580
Abstract
A tubular molecular rotor B-Ta@B (1) and boron drum Ta@B (2) with the highest coordination number of twenty in chemistry are observed via a joint photoelectron spectroscopy and first-principles theory investigation.
摘要
通过光电子能谱和第一性原理理论联合研究，观察到一种管状分子转子B-Ta@B (1)和硼鼓Ta@B (2)，它们在化学中具有最高的二十配位。
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