Vu Tuan V, Ondracek Jakub, Zdímal Vladimir, Schwarz Jaroslav, Delgado-Saborit Juana Maria, Harrison Roy M
Division of Environmental Health & Risk Management, School of Geography, Earth & Environmental Sciences, University of Birmingham, Edgbaston, Birmingham B15 2TT UK.
Institute of Chemical Process Fundamentals of the ASCR (ICPF), Prague, 165 02 Czech Republic.
Air Qual Atmos Health. 2017;10(1):1-14. doi: 10.1007/s11869-016-0424-1. Epub 2016 Aug 25.
The physical properties of indoor particles were measured with an Scanning Mobility Particle Sizer (SMPS) system (14.6-850 nm), an Aerodynamic Particle Sizer (APS, 0.54-18 μm) and an Hygroscopic Tandem Differential Mobility Analyzer (H-TDMA) in an apartment located in an urban background site in Prague (Czech Republic) from 15 August to 8 September, 2014. The total particle maximum number concentration was 9.38 × 10, 1.46 × 10, 2.89 × 10, 2.25 × 10 and 1.57 × 10 particles cm for particles released from vacuum cleaning, soap/W5 cleaning spray, smoking, incense burning and cooking (frying) activities, respectively. Particles emitted from cleaning activities showed unimodal number size distributions, with the majority of particles (>98.2 %) in the ultrafine size range (Dp <100 nm) and modes at a diameter of 19.8 nm for vacuum cleaning and 30.6 nm for soap/W5 cleaning. Smoking and incense burning predominantly generated particles in the accumulation mode with a count median diameter around 90-150 nm while cooking emissions showed a bimodal structure with a main mode at 47.8 nm. Particles from vacuum cleaning, incense burning, smoking and cooking emissions were found to be "nearly hydrophobic" with an average growth factor (G) around 1.01-1.10, while particles emitted from desk cleaning using organic compounds were found to be "less-hygroscopic" (G ∼1.12-1.16). Based on an adjusted MPPD model with a consideration of the hygroscopic properties of particles, the total lung deposition fractions of these particles by number when they penetrate into the human lung were 0.73 ± 0.02, 0.62 ± 0.03, 0.37 ± 0.03, 0.32 ± 0.03 and 0.49 ± 0.02 for vacuum cleaning, desk cleaning, smoking, incense burning and cooking, respectively.
2014年8月15日至9月8日期间,在捷克共和国布拉格一个城市背景站点的一套公寓内,使用扫描迁移率粒径谱仪(SMPS,测量范围14.6 - 850纳米)、气动力学粒径谱仪(APS,测量范围0.54 - 18微米)和吸湿串联差分迁移率分析仪(H - TDMA)对室内颗粒物的物理特性进行了测量。对于由真空清洁、肥皂/W5清洁喷雾、吸烟、焚香和烹饪(油炸)活动产生的颗粒物,其总颗粒物最大数浓度分别为9.38×10、1.46×10、2.89×10、2.25×10和1.57×10个/立方厘米。清洁活动产生的颗粒物呈现单峰数量粒径分布,大多数颗粒物(>98.2%)处于超细粒径范围(Dp <100纳米),真空清洁产生颗粒物的模态直径为19.8纳米,肥皂/W5清洁产生颗粒物的模态直径为30.6纳米。吸烟和焚香主要产生积聚模态的颗粒物,计数中值直径约为90 - 150纳米,而烹饪排放呈现双峰结构,主模态直径为47.8纳米。发现真空清洁、焚香、吸烟和烹饪排放产生的颗粒物“近乎疏水”,平均增长因子(G)约为1.01 - 1.10,而使用有机化合物进行桌面清洁产生的颗粒物“吸湿性较弱”(G ∼1.12 - 1.16)。基于考虑颗粒物吸湿特性的调整后的MPPD模型,这些颗粒物进入人体肺部时按数量计的总肺沉积分数,真空清洁为0.73±0.02,桌面清洁为0.62±0.03,吸烟为0.37±0.03,焚香为0.32±0.03,烹饪为0.49±0.02。