Department of Civil and Environmental Engineering, Carleton University, 1125 Colonel ByDrive, Ottawa, ON K1S 5B6, Canada.
Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, ON K1S 5B6, Canada.
J Environ Sci (China). 2017 Jan;51:256-264. doi: 10.1016/j.jes.2016.05.033. Epub 2016 Jul 25.
Endocrine disrupting compounds (EDCs) and pharmaceuticals pose a challenge for water and wastewater treatment because they exist at very low concentrations in the presence of substances at much higher concentrations competing for adsorption sites. Sub-micron sized resin particles (approximately 300nm in diameter) (SMR) were tested to evaluate their potential as a treatment for EDCs including: 17-β estradiol (E2), 17-α ethinylestradiol (EE2), estrone (E1), bisphenol A (BPA), and diethylstilbestrol (DES) as well as 12 pharmaceuticals. SMR were able to remove 98% of spiked E2, 80% of EE2, 87% of BPA, and up to 97% of DES from water. For a 0.5ppm mixture of E2, EE2, E1, BPA and DES, the minimum removal was 24% (E2) and the maximum was 49% (DES). They were also able to remove the pharmaceuticals from deionized water and wastewater. Overall, SMR are a promising advanced treatment for removal of both EDCs and pharmaceuticals.
内分泌干扰化合物 (EDCs) 和药物对水处理和废水处理构成了挑战,因为它们在存在高浓度竞争吸附位点物质的情况下,浓度非常低。亚微米大小的树脂颗粒 (直径约 300nm) (SMR) 已被测试,以评估其作为 EDCs 处理剂的潜力,包括:17-β 雌二醇 (E2)、17-α 乙炔基雌二醇 (EE2)、雌酮 (E1)、双酚 A (BPA) 和己烯雌酚 (DES) 以及 12 种药物。SMR 能够去除水中 98%的 E2、80%的 EE2、87%的 BPA 和高达 97%的 DES。对于 0.5ppm 的 E2、EE2、E1、BPA 和 DES 混合物,最小去除率为 24%(E2),最大去除率为 49%(DES)。它们还能够从去离子水和废水中去除这些药物。总体而言,SMR 是一种很有前途的高级处理方法,可用于去除 EDCs 和药物。