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使用亚微米级树脂颗粒去除水中和废水中的内分泌干扰化合物和药物。

Use of sub-micron sized resin particles for removal of endocrine disrupting compounds and pharmaceuticals from water and wastewater.

机构信息

Department of Civil and Environmental Engineering, Carleton University, 1125 Colonel ByDrive, Ottawa, ON K1S 5B6, Canada.

Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, ON K1S 5B6, Canada.

出版信息

J Environ Sci (China). 2017 Jan;51:256-264. doi: 10.1016/j.jes.2016.05.033. Epub 2016 Jul 25.

Abstract

Endocrine disrupting compounds (EDCs) and pharmaceuticals pose a challenge for water and wastewater treatment because they exist at very low concentrations in the presence of substances at much higher concentrations competing for adsorption sites. Sub-micron sized resin particles (approximately 300nm in diameter) (SMR) were tested to evaluate their potential as a treatment for EDCs including: 17-β estradiol (E2), 17-α ethinylestradiol (EE2), estrone (E1), bisphenol A (BPA), and diethylstilbestrol (DES) as well as 12 pharmaceuticals. SMR were able to remove 98% of spiked E2, 80% of EE2, 87% of BPA, and up to 97% of DES from water. For a 0.5ppm mixture of E2, EE2, E1, BPA and DES, the minimum removal was 24% (E2) and the maximum was 49% (DES). They were also able to remove the pharmaceuticals from deionized water and wastewater. Overall, SMR are a promising advanced treatment for removal of both EDCs and pharmaceuticals.

摘要

内分泌干扰化合物 (EDCs) 和药物对水处理和废水处理构成了挑战,因为它们在存在高浓度竞争吸附位点物质的情况下,浓度非常低。亚微米大小的树脂颗粒 (直径约 300nm) (SMR) 已被测试,以评估其作为 EDCs 处理剂的潜力,包括:17-β 雌二醇 (E2)、17-α 乙炔基雌二醇 (EE2)、雌酮 (E1)、双酚 A (BPA) 和己烯雌酚 (DES) 以及 12 种药物。SMR 能够去除水中 98%的 E2、80%的 EE2、87%的 BPA 和高达 97%的 DES。对于 0.5ppm 的 E2、EE2、E1、BPA 和 DES 混合物,最小去除率为 24%(E2),最大去除率为 49%(DES)。它们还能够从去离子水和废水中去除这些药物。总体而言,SMR 是一种很有前途的高级处理方法,可用于去除 EDCs 和药物。

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