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超声振动对高合金 TiAl 微观结构和力学性能的影响。

Effects of ultrasonic vibration on the microstructure and mechanical properties of high alloying TiAl.

机构信息

School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China.

出版信息

Sci Rep. 2017 Jan 24;7:41463. doi: 10.1038/srep41463.

Abstract

To modify the microstructure and enhance performances, the ultrasonic vibration is applied in the mould casting of TiAl alloy. The effects and mechanism of ultrasonic vibration on the solidifying microstructure and mechanical properties are investigated and the model for predicting lamellar colony size is established. After ultrasonic vibration, the coarse microstructure is well modified and lamellar colony is refined from 534 μm to 56 μm. Most of precipitated phases are dissolved into the lamellar colony leading to a homogenous element distribution. The phase ratio of α-TiAl and γ-TiAl is increased, and the chemical composition is promoted to more close to equilibrium level by weakening the influence of β-alloying elements. The microhardness and yield strength are gradually improved by 23.72% and 181.88% due to the fine grain strengthening, while the compressive strength is enhanced by 24.47% through solution strengthening. The critical ultrasonic intensity (I) for TiAl alloy is estimated at 220 W cm and the model for average lamellar colony size is established as . The ultrasonic refinement efficiency exponentially increases as the ultrasonic vibration time with a theoretic limit maximum value of E = 88% and the dominating refinement mechanism by ultrasonic vibration is the cavitation-enhanced nucleation rather than cavitation-induced dendrite fragmentation.

摘要

为了改善微观结构和提高性能,在 TiAl 合金的模具铸造中应用了超声振动。研究了超声振动对凝固微观结构和力学性能的影响和机制,并建立了预测片层组织尺寸的模型。经过超声振动后,粗大的微观结构得到了很好的改善,片层组织从 534μm细化到 56μm。大部分析出相溶解在片层组织中,导致元素分布均匀。α-TiAl 和 γ-TiAl 的相比例增加,化学成分通过削弱β 合金元素的影响而更接近平衡水平。由于细晶强化,显微硬度和屈服强度逐渐提高了 23.72%和 181.88%,而通过固溶强化,抗压强度提高了 24.47%。TiAl 合金的临界超声强度(I)估计为 220 W/cm,平均片层组织尺寸的模型建立为 。随着超声振动时间的增加,超声细化效率呈指数增长,理论上的最大效率值为 E=88%,超声振动的主要细化机制是空化增强形核,而不是空化诱导枝晶破碎。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f8b9/5259764/bb80c460f751/srep41463-f1.jpg

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