通过利用仲氢诱导极化的核磁共振揭示钯纳米晶体催化剂上氢的面依赖成对加成。
Facet dependent pairwise addition of hydrogen over Pd nanocrystal catalysts revealed via NMR using para-hydrogen-induced polarization.
作者信息
Wang Weiyu, Xu Jun, Zhao Yanxi, Qi Guodong, Wang Qiang, Wang Chao, Li Jinlin, Deng Feng
机构信息
National Center for Magnetic Resonance in Wuhan, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China.
Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan 430074, China.
出版信息
Phys Chem Chem Phys. 2017 Apr 5;19(14):9349-9353. doi: 10.1039/c7cp00352h.
We demonstrated the facet dependence of pairwise addition of hydrogen in heterogeneous catalysis over Pd nanocrystal catalysts via NMR using para-hydrogen-induced polarization.
我们通过利用仲氢诱导极化的核磁共振（NMR）技术，证明了在钯纳米晶体催化剂上的多相催化中，氢的成对添加对晶面的依赖性。
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