Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, Norrköping SE-60174, Sweden.
Nat Commun. 2017 Jan 31;8:14214. doi: 10.1038/ncomms14214.
Temperature is one of the most important environmental stimuli to record and amplify. While traditional thermoelectric materials are attractive for temperature/heat flow sensing applications, their sensitivity is limited by their low Seebeck coefficient (∼100 μV K). Here we take advantage of the large ionic thermoelectric Seebeck coefficient found in polymer electrolytes (∼10,000 μV K) to introduce the concept of ionic thermoelectric gating a low-voltage organic transistor. The temperature sensing amplification of such ionic thermoelectric-gated devices is thousands of times superior to that of a single thermoelectric leg in traditional thermopiles. This suggests that ionic thermoelectric sensors offer a way to go beyond the limitations of traditional thermopiles and pyroelectric detectors. These findings pave the way for new infrared-gated electronic circuits with potential applications in photonics, thermography and electronic-skins.
温度是记录和放大的最重要的环境刺激之一。虽然传统的热电材料在温度/热流感应应用中很有吸引力,但它们的灵敏度受到其低 Seebeck 系数(约 100 μV K)的限制。在这里,我们利用聚合物电解质中发现的大离子热电 Seebeck 系数(约 10,000 μV K),引入了离子热电门控低电压有机晶体管的概念。与传统热电堆中的单个热电腿相比,这种离子热电门控器件的温度感应放大效果要好数千倍。这表明离子热电传感器为超越传统热电堆和热释电探测器的限制提供了一种途径。这些发现为新型红外门控电子电路铺平了道路,有望在光子学、热成像和电子皮肤等领域得到应用。