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通过优化阴离子基团中的键合电子分布来增强晶体的光学各向异性。

Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups.

作者信息

Lei Bing-Hua, Yang Zhihua, Pan Shilie

机构信息

Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China.

出版信息

Chem Commun (Camb). 2017 Mar 2;53(19):2818-2821. doi: 10.1039/c6cc09986f.

DOI:10.1039/c6cc09986f
PMID:28144658
Abstract

The response electron distribution anisotropy (REDA) approximation was proposed to analyze the relationship between optical anisotropy and distribution of bonding electrons in compounds. Further, the optical anisotropy of tetrahedral chromophore compounds with common small birefringence can be enhanced and excellent nonlinear optical properties can be obtained by optimizing the distribution.

摘要

提出了响应电子分布各向异性(REDA)近似方法来分析化合物中光学各向异性与成键电子分布之间的关系。此外,通过优化分布,可以增强具有常见小双折射的四面体发色团化合物的光学各向异性,并获得优异的非线性光学性质。

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