Lei Bing-Hua, Yang Zhihua, Pan Shilie
Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences; Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China.
Chem Commun (Camb). 2017 Mar 2;53(19):2818-2821. doi: 10.1039/c6cc09986f.
The response electron distribution anisotropy (REDA) approximation was proposed to analyze the relationship between optical anisotropy and distribution of bonding electrons in compounds. Further, the optical anisotropy of tetrahedral chromophore compounds with common small birefringence can be enhanced and excellent nonlinear optical properties can be obtained by optimizing the distribution.
提出了响应电子分布各向异性(REDA)近似方法来分析化合物中光学各向异性与成键电子分布之间的关系。此外,通过优化分布,可以增强具有常见小双折射的四面体发色团化合物的光学各向异性,并获得优异的非线性光学性质。