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无枝晶、高倍率、长寿命锂金属电池,采用 3D 交联网络聚合物电解质。

Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte.

机构信息

Engineering Laboratory for Functionalized Carbon Materials and Engineering Laboratory for the Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055, P. R. China.

Tsinghua-Berkeley Shenzhen Institute, Tsinghua University, Shenzhen, 518055, P. R. China.

出版信息

Adv Mater. 2017 Apr;29(13). doi: 10.1002/adma.201604460. Epub 2017 Feb 1.

Abstract

A 3D network gel polymer electrolyte (3D-GPE) is designed for lithium metal batteries and prepared by an initiator-free one-pot ring-opening polymerization technique. This 3D-GPE exhibits an unprecedented combination of mechanical strength, ionic conductivity, and more importantly, effective suppression of Li dendrite growth. The produced lithium-based battery presents long life, high rate, and excellent safety.

摘要

一种用于锂金属电池的 3D 网络凝胶聚合物电解质(3D-GPE)通过无引发剂一锅开环聚合技术制备。这种 3D-GPE 具有前所未有的机械强度、离子电导率,更重要的是,有效抑制了锂枝晶生长。所制备的基于锂的电池具有长寿命、高倍率和优异的安全性。

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