School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.
Chemical Engineering Department, Engineering College, Baghdad University, P.O. Box 47024, Aljadria, Baghdad, Iraq.
Int J Biol Macromol. 2017 May;98:233-239. doi: 10.1016/j.ijbiomac.2017.01.119. Epub 2017 Jan 29.
In this work, mesoporous-activated carbon (CSAC) was prepared from chitosan flakes (CS) via single-step sodium hydroxide activation for the adsorption of methylene blue (MB). CSAC was prepared using different impregnation ratios of NaOH:CS (1:1, 2:1, 3:1, and 4:1) at 800°C for 90min. The adsorption performance of CSAC was evaluated for MB at different adsorption variables, such MB initial concentrations (25-400mg/L), solution pH (3-11), and temperature (30-50°C). The adsorption isotherm data of CSAC-MB were well fitted to Langmuir model with a maximum adsorption capacity 143.53mg/g at 50°C. Best representation of kinetic data was obtained by the pseudo-second order model. CSAC exhibited excellent adsorption uptake for MB and can potentially be used for other cationic dyes.
在这项工作中,通过一步氢氧化钠活化法从壳聚糖薄片(CS)制备了中孔活性炭(CSAC),用于吸附亚甲基蓝(MB)。CSAC 是使用不同浸渍比的 NaOH:CS(1:1、2:1、3:1 和 4:1)在 800°C 下反应 90min 制得的。在不同的吸附变量下,如 MB 的初始浓度(25-400mg/L)、溶液 pH(3-11)和温度(30-50°C)下,评估了 CSAC 对 MB 的吸附性能。CSAC-MB 的吸附等温线数据很好地符合朗缪尔模型,在 50°C 时最大吸附容量为 143.53mg/g。准二级动力学模型对动力学数据的拟合效果最好。CSAC 对 MB 具有优异的吸附能力,有望用于其他阳离子染料。