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由壳聚糖薄片通过一步氢氧化钠活化法制备的中孔活性炭,用于吸附亚甲基蓝。

Mesoporous-activated carbon prepared from chitosan flakes via single-step sodium hydroxide activation for the adsorption of methylene blue.

机构信息

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.

Chemical Engineering Department, Engineering College, Baghdad University, P.O. Box 47024, Aljadria, Baghdad, Iraq.

出版信息

Int J Biol Macromol. 2017 May;98:233-239. doi: 10.1016/j.ijbiomac.2017.01.119. Epub 2017 Jan 29.

Abstract

In this work, mesoporous-activated carbon (CSAC) was prepared from chitosan flakes (CS) via single-step sodium hydroxide activation for the adsorption of methylene blue (MB). CSAC was prepared using different impregnation ratios of NaOH:CS (1:1, 2:1, 3:1, and 4:1) at 800°C for 90min. The adsorption performance of CSAC was evaluated for MB at different adsorption variables, such MB initial concentrations (25-400mg/L), solution pH (3-11), and temperature (30-50°C). The adsorption isotherm data of CSAC-MB were well fitted to Langmuir model with a maximum adsorption capacity 143.53mg/g at 50°C. Best representation of kinetic data was obtained by the pseudo-second order model. CSAC exhibited excellent adsorption uptake for MB and can potentially be used for other cationic dyes.

摘要

在这项工作中,通过一步氢氧化钠活化法从壳聚糖薄片(CS)制备了中孔活性炭(CSAC),用于吸附亚甲基蓝(MB)。CSAC 是使用不同浸渍比的 NaOH:CS(1:1、2:1、3:1 和 4:1)在 800°C 下反应 90min 制得的。在不同的吸附变量下,如 MB 的初始浓度(25-400mg/L)、溶液 pH(3-11)和温度(30-50°C)下,评估了 CSAC 对 MB 的吸附性能。CSAC-MB 的吸附等温线数据很好地符合朗缪尔模型,在 50°C 时最大吸附容量为 143.53mg/g。准二级动力学模型对动力学数据的拟合效果最好。CSAC 对 MB 具有优异的吸附能力,有望用于其他阳离子染料。

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