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Br-PADAP 嵌入醋酸纤维素电纺纳米纤维中:用于目视铀识别的比色传感器条。

Br-PADAP embedded in cellulose acetate electrospun nanofibers: Colorimetric sensor strips for visual uranyl recognition.

机构信息

School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

出版信息

J Hazard Mater. 2017 May 5;329:205-210. doi: 10.1016/j.jhazmat.2017.01.038. Epub 2017 Jan 23.

Abstract

In this work, a new visual colorimetric strip based on cellulose acetate nanofiber mats modified by 2-(5-Bromo-2-pyridylazo)-5-(diethylamino) phenol was successfully prepared via electrospinning technology. The prepared colorimetric strip showed high sensitivity towards UO with the yellow-to-purple color change signal. Upon the optimal conditions of solution pH at 6.0 and response time for 80min, the detection limit for UO can reach 50 ppb. Moreover, the strip also exhibited excellent anti-interference ability in the presence of other metal ions. In order to achieve the quantitative detection for UO, a color-differentiation map was established, which was prepared from converted H values. Finally, the strip was also used to detect UO in the seawater and showed high sensitivity.

摘要

在这项工作中,我们通过静电纺丝技术成功制备了一种基于醋酸纤维素纳米纤维垫修饰 2-(5-溴-2-吡啶偶氮)-5-(二乙氨基)苯酚的新型可视化比色条。该比色条对 UO 表现出高灵敏度,具有黄色到紫色的颜色变化信号。在最佳条件下,溶液 pH 值为 6.0,响应时间为 80min,UO 的检测限可达到 50ppb。此外,该条带在存在其他金属离子的情况下也表现出优异的抗干扰能力。为了实现 UO 的定量检测,我们建立了一个基于转换后的 H 值的颜色区分图谱。最后,该条带还用于检测海水中的 UO,表现出高灵敏度。

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