有机铁配合物的新化学和立体化学应用

New Chemical and Stereochemical Applications of Organoiron Complexes.

作者信息

Fatiadi Alexander J

机构信息

National Institute of Standards and Technology, Gaithersburg, MD 20899.

出版信息

J Res Natl Inst Stand Technol. 1991 Jan-Feb;96(1):1-113. doi: 10.6028/jres.096.002.

DOI:10.6028/jres.096.002

PMID:28184103

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4961068/

Abstract

The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η-CH) Fe(CO)(PPh)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO) group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

摘要

本综述的目的是对快速发展的有机金属配合物化学，特别是在不对称和立体选择性反应中有用的有机铁配合物化学进行当前概述。还涵盖了与手性助剂[(η-CH)Fe(CO)(PPh)]结合的α,β-不饱和酰基配体的立体选择性反应以及有机铁配合物在天然产物合成中的新应用。讨论了Fe(CO)基团对烯烃或共轭二烯的机理方面和稳定作用。还包括了关于铁在生物反应中的特殊作用的近期工作的简要总结。