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三[（4,7,13,16,21,24-六氧杂-1,10-二氮杂双环-[8.8.8]二十六烷-κ）铷]铷九锡化物的晶体结构

Crystal structure of tris[(4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo-[8.8.8]hexa-cosane-κ,)rubidium] rubidium nona-stannide.

作者信息

Klein Wilhelm, He Haiyan, Fässler Thomas F

机构信息

Technische Universität München, Department of Chemistry, Lichtenbergstr. 4, 85747 Garching, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Jan 13;73(Pt 2):147-151. doi: 10.1107/S2056989017000172. eCollection 2017 Feb 1.

DOI:10.1107/S2056989017000172
PMID:28217330
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5290553/
Abstract

The crystal structure of the title compound, [Rb(CHNO)]RbSn, consists of deltahedral [Sn] cluster anions, Rb cations and cryptand mol-ecules, which partially sequester the cations. Those cations, which are not coordinated by cryptand mol-ecules, are neighboured directly to the [Sn] clusters and inter-connect them to form [RbSn] chains. These chains extend parallel to [001] and are arranged in a pseudo-hexa-gonal rod packing, separated by the Rb-cryptand complex cations.

摘要

标题化合物[Rb(CHNO)]RbSn的晶体结构由三角面[Sn]簇阴离子、Rb阳离子和穴状配体分子组成，穴状配体分子部分螯合阳离子。那些未与穴状配体分子配位的阳离子直接与[Sn]簇相邻，并将它们相互连接形成[RbSn]链。这些链平行于[001]方向延伸，并以假六方棒状堆积排列，被Rb-穴状配体复合阳离子隔开。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32c6/5290553/ec13e88190d1/e-73-00147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32c6/5290553/90c2c19d4245/e-73-00147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32c6/5290553/ec13e88190d1/e-73-00147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32c6/5290553/90c2c19d4245/e-73-00147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/32c6/5290553/ec13e88190d1/e-73-00147-fig2.jpg

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