Institute of Medicine and Material Applied Technologies, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, P. R. China.
Sci Rep. 2017 Feb 20;7:42932. doi: 10.1038/srep42932.
In the present work, a facile and efficient fabrication method has been developed for creating super-hydrophobic coatings of silver-doped TiO@polycarbonate (TiO (Ag)@PC) on the substrates of different materials with photocatalytic self-cleaning performances simply by the "dipping and drying" process. The substrates were first patterned with glue and then deposited with the dopamine-capped TiO (Ag)@PC (DA-TiO (Ag)@PC) nanocomposites, followed by the further etching with dimethylbenzene. The so prepared super-hydrophobic E-DA-TiO(Ag)@PC coatings could present the lotus leaf-like porous architectures, high adhesion stability, and especially the visible-light photocatalysis for organic contaminant degradation, thus promising the wide outdoor and indoor applications like water proofing, metal erosion protection, and surface self-cleaning.
在本工作中,通过“浸渍和干燥”工艺,开发了一种简便有效的方法,在不同材料的基底上制备具有光催化自清洁性能的银掺杂 TiO@聚碳酸酯(TiO(Ag)@PC)超疏水涂层。基底先用胶水进行图案化处理,然后沉积多巴胺包覆的 TiO(Ag)@PC(DA-TiO(Ag)@PC)纳米复合材料,再用二甲苯进一步刻蚀。所制备的超疏水 E-DA-TiO(Ag)@PC 涂层可呈现出类似荷叶的多孔结构,具有高附着力稳定性,特别是可见光光催化有机污染物降解,因此有望在户外和室内得到广泛应用,如防水、金属腐蚀防护和表面自清洁。