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具有可见光光催化自清洁污染物降解功能的各种材料基底上制备的超疏水掺银 TiO @聚碳酸酯涂层。

Super-hydrophobic Silver-Doped TiO @ Polycarbonate Coatings Created on Various Material Substrates with Visible-Light Photocatalysis for Self-Cleaning Contaminant Degradation.

机构信息

Institute of Medicine and Material Applied Technologies, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, P. R. China.

出版信息

Sci Rep. 2017 Feb 20;7:42932. doi: 10.1038/srep42932.

Abstract

In the present work, a facile and efficient fabrication method has been developed for creating super-hydrophobic coatings of silver-doped TiO@polycarbonate (TiO (Ag)@PC) on the substrates of different materials with photocatalytic self-cleaning performances simply by the "dipping and drying" process. The substrates were first patterned with glue and then deposited with the dopamine-capped TiO (Ag)@PC (DA-TiO (Ag)@PC) nanocomposites, followed by the further etching with dimethylbenzene. The so prepared super-hydrophobic E-DA-TiO(Ag)@PC coatings could present the lotus leaf-like porous architectures, high adhesion stability, and especially the visible-light photocatalysis for organic contaminant degradation, thus promising the wide outdoor and indoor applications like water proofing, metal erosion protection, and surface self-cleaning.

摘要

在本工作中,通过“浸渍和干燥”工艺,开发了一种简便有效的方法,在不同材料的基底上制备具有光催化自清洁性能的银掺杂 TiO@聚碳酸酯(TiO(Ag)@PC)超疏水涂层。基底先用胶水进行图案化处理,然后沉积多巴胺包覆的 TiO(Ag)@PC(DA-TiO(Ag)@PC)纳米复合材料,再用二甲苯进一步刻蚀。所制备的超疏水 E-DA-TiO(Ag)@PC 涂层可呈现出类似荷叶的多孔结构,具有高附着力稳定性,特别是可见光光催化有机污染物降解,因此有望在户外和室内得到广泛应用,如防水、金属腐蚀防护和表面自清洁。

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