叠氮基和四唑并[1,2,4,5]-四嗪 1,2,4,5-四氧化物。
Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides.
机构信息
Explosive Science and Shock Physics, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
Laboratory for the Structure of Matter, Naval Research Laboratory, 4555 Overlook Ave., Washington, DC, 20375, USA.
出版信息
Angew Chem Int Ed Engl. 2017 Mar 20;56(13):3575-3578. doi: 10.1002/anie.201612496. Epub 2017 Feb 23.
This study presents the synthesis and characterization of the oxidation products of 3,6-diazido-1,2,4,5-tetrazine (1) and 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine (2). 3,6-Diazido-1,2,4,5-tetrazine-1,4-dioxide was produced from oxidation with peroxytrifluoroacetic acid, and more effectively using hypofluorous acid, and 2 can be oxidized to two different products, 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine mono-N-oxide and di-N-oxide. These N-oxide compounds display promising performance properties as energetic materials.
本研究介绍了 3,6-二叠氮-1,2,4,5-四嗪（1）和 6-氨基-[1,5-b]四唑-1,2,4,5-四嗪（2）氧化产物的合成与表征。过三氟乙酸氧化可得到 3,6-二叠氮-1,2,4,5-四嗪-1,4-二氧化物，而使用次氟酸则更为有效，2 可被氧化为两种不同的产物，6-氨基-[1,5-b]四唑-1,2,4,5-四嗪单-N-氧化物和二-N-氧化物。这些 N-氧化物化合物作为高能材料表现出有前景的性能。
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