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过冷液体在剪切下的瞬态非均匀流动模式。

Transient inhomogeneous flow patterns in supercooled liquids under shear.

机构信息

ETH Zurich, Department of Materials, Vladimir-Prelog-Weg 1-5/10, CH-8093 Zurich, Switzerland.

School of Mathematical, Physical and Computational Sciences, University of Reading, Reading RG6 6AX, UK.

出版信息

Soft Matter. 2017 Mar 15;13(11):2192-2200. doi: 10.1039/c7sm00178a.

Abstract

Supercooled liquids and other soft glassy systems show characteristic spatial inhomogeneities in their local dynamical properties. Using detailed molecular dynamics simulations, we find that for sufficiently low temperatures and sufficiently high shear rates supercooled liquids also show transient inhomogeneous flow patterns (shear banding) in the start-up of steady shear flow, similar to what has already been observed for many other soft glassy systems. We verify that the onset of transient shear banding coincides quite well with the appearance of a stress overshoot for temperatures in the supercooled regime. We find that the slower bands adapt less well to the imposed deformation and therefore accumulate higher shear stresses compared to the fast bands at comparable local shear rates. Our results also indicate that the shear rates of the fast and slow bands are adjusted such that the local dissipation rate is approximately the same in both bands.

摘要

过冷液体和其他软玻璃态系统在其局部动力学性质上表现出特征空间不均匀性。使用详细的分子动力学模拟,我们发现对于足够低的温度和足够高的剪切速率,过冷液体在稳态剪切流动的启动中也表现出瞬态非均匀流动模式(剪切带),类似于已经观察到的许多其他软玻璃态系统。我们验证了瞬态剪切带的出现与过冷区温度下的应力过冲的出现非常吻合。我们发现较慢的带适应变形的能力较差,因此与在可比局部剪切速率下的快带相比,积累更高的剪切应力。我们的结果还表明,快带和慢带的剪切速率进行了调整,使得在两个带中的局部耗散率大致相同。

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