Vránová Iva, Kremláček Vít, Erben Milan, Turek Jan, Jambor Roman, Růžička Aleš, Alonso Mercedes, Dostál Libor
Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ - 532 10, Pardubice, Czech Republic.
Eenheid Algemene Chemie (ALGC), Member of the QCMM VUB-UGent Alliance Research Group, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium.
Dalton Trans. 2017 Mar 14;46(11):3556-3568. doi: 10.1039/c7dt00095b.
N,C,N-Chelated pnictinidenes ArE [where E = As (1), Sb (2) or Bi (3); Ar = CH-2,6-(CH[double bond, length as m-dash]Nt-Bu)] were used as ligands for the coordination of transition metal carbonyls. Thus, the reaction of 1-3 with [M(CO)THF] (where M = Cr, W) or [Mo(CO)(MeN)] gave complexes [(ArE)M(CO)] [where E = As and M = Cr (1a), Mo (1b), W (1c); E = Sb and M = Cr (2a), Mo (2b), W (2c); E = Bi and M = Cr (3a), Mo (3b), W (3c)]. Analogously, the treatment of 1-3 with [Fe(CO)] resulted in the formation of the complexes [(ArE)Fe(CO)] [where E = As (1d), Sb (2d) or Bi (3d)]. All compounds were characterized by H and C NMR spectroscopy, Raman, IR and UV-Vis spectroscopy. The molecular structures of the majority of the compounds (except 1b and 1c) were also determined by the single-crystal X-ray diffraction analysis. Furthermore, the structure and bonding of the title compounds have also been thoroughly investigated using a computational approach.
N、C、N-螯合的磷族元素化合物ArE（其中E = As（1）、Sb（2）或Bi（3）；Ar = CH-2,6-(CH[双键，长度如间位短线]-Nt-Bu)）被用作过渡金属羰基配合物的配体。因此，1-3与[M(CO)THF]（其中M = Cr、W）或[Mo(CO)(MeN)]反应得到配合物[(ArE)M(CO)]（其中E = As且M = Cr（1a）、Mo（1b）、W（1c）；E = Sb且M = Cr（2a）、Mo（2b）、W（2c）；E = Bi且M = Cr（3a）、Mo（3b）、W（3c））。类似地，1-3与[Fe(CO)]反应生成配合物[(ArE)Fe(CO)]（其中E = As（1d）、Sb（2d）或Bi（3d））。所有化合物均通过氢谱和碳谱核磁共振、拉曼光谱、红外光谱和紫外-可见光谱进行表征。大多数化合物（1b和1c除外）的分子结构也通过单晶X射线衍射分析确定。此外，还使用计算方法对标题化合物的结构和键合进行了深入研究。
