Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China; State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
J Hazard Mater. 2017 Jun 5;331:1-12. doi: 10.1016/j.jhazmat.2017.02.030. Epub 2017 Feb 20.
A novel flower-like three-dimensional BiOBr/BiOI/FeO heterojunction photocatalyst was synthesized using a simple in situ co-precipitation method at room temperature. The hybrid composites were characterized by a couple of techniques including X-ray powder diffraction, scanning electron microscope, transmission electron microscopy, ultraviolet-visible diffuse reflection spectroscopy, Brunauer-Emmett-Teller, X-ray photo-electron spectroscopy, photoluminescence technique, and vibrating sample magnetometer. FeO nanoparticles were perfectly loaded on the surface of BiOBr/BiOI microspheres. The recyclable magnetic BiOBr/BiOI/FeO was employed to degrade TBBPA under visible light irradiation. The optimal removal efficiency of the ternary BiOBr/BiOI/FeO (2:2:0.5) nanocomposite reached up to 98.5% for TBBPA in aqueous solution. The superior photocatalytic activity of BiOBr/BiOI/FeO was mainly ascribed to large surface area and appropriate energy gaps, resulting in the effective adsorption and separation of electrons-hole pairs. The photogenerated reactive species determined by free radicals trapping experiments revealed that the excellent catalytic activity was primarily driven by O radical. The photocatalytic degradation kinetics and a detailed mechanism were also proposed. Result demonstrated that the BiOBr/BiOI/FeO can be magnetically recycled, and maintain high photocatalytic activity after reuse over five cycles. It suggested that the synthesized material had a potentially promising application for TBBPA removal by photocatalytic degradation from wastewater.
一种新型花状三维 BiOBr/BiOI/FeO 异质结光催化剂是通过室温下的简单原位共沉淀法合成的。采用 X 射线粉末衍射、扫描电子显微镜、透射电子显微镜、紫外-可见漫反射光谱、Brunauer-Emmett-Teller、X 射线光电子能谱、光致发光技术和振动样品磁强计等几种技术对混合复合材料进行了表征。FeO 纳米颗粒完美地负载在 BiOBr/BiOI 微球的表面上。可回收的磁性 BiOBr/BiOI/FeO 被用于在可见光照射下降解 TBBPA。三元 BiOBr/BiOI/FeO(2:2:0.5)纳米复合材料对水溶液中 TBBPA 的最佳去除效率高达 98.5%。BiOBr/BiOI/FeO 的优异光催化活性主要归因于大的比表面积和适当的能隙,从而有效地实现了电子-空穴对的有效吸附和分离。通过自由基捕获实验确定的光生活性物质表明,优异的催化活性主要是由 O 自由基驱动的。还提出了光催化降解动力学和详细的机理。结果表明,BiOBr/BiOI/FeO 可以通过磁性回收,并在重复使用五次后保持高的光催化活性。这表明该合成材料具有通过光催化降解从废水中去除 TBBPA 的潜在应用前景。
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