Koumatos K, Muehlemann A
Department of Mathematics, University of Sussex, Pevensey 2 Building, Brighton, England.
Department of Civil Engineering, Davis Hall, University of California Berkeley, Berkeley, USA.
Acta Crystallogr A Found Adv. 2017 Mar 1;73(Pt 2):115-123. doi: 10.1107/S2053273316020350. Epub 2017 Feb 7.
The identification of orientation relationships (ORs) plays a crucial role in the understanding of solid phase transformations. In steels, the most common models of ORs are the ones by Nishiyama-Wassermann (NW) and Kurdjumov-Sachs (KS). The defining feature of these and other OR models is the matching of directions and planes in the parent face-centred cubic γ phase to ones in the product body-centred cubic/tetragonal α/α' phase. In this article a novel method that identifies transformation strains with ORs is introduced and used to develop a new strain-based approach to phase-transformation models in steels. Using this approach, it is shown that the transformation strains that leave a close-packed plane in the γ phase and a close-packed direction within that plane unrotated are precisely those giving rise to the NW and KS ORs when a cubic product phase is considered. Further, it is outlined how, by choosing different pairs of unrotated planes and directions, other common ORs such as the ones by Pitsch and Greninger-Troiano can be derived. One of the advantages of our approach is that it leads to a natural generalization of the NW, KS and other ORs for different ratios of tetragonality r of the product body-centred tetragonal α' phase. These generalized ORs predict a sharpening of the transformation textures with increasing tetragonality and are thus in qualitative agreement with experiments on steels with varying alloy concentration.
取向关系(ORs)的识别在理解固态相变过程中起着至关重要的作用。在钢中,最常见的OR模型是西山-瓦瑟曼(NW)模型和库尔久莫夫-萨克斯(KS)模型。这些以及其他OR模型的定义特征是母面心立方γ相中的方向和平面与产物体心立方/四方α/α'相中的方向和平面相匹配。在本文中,介绍了一种通过ORs识别转变应变的新方法,并将其用于开发一种基于应变的新方法来建立钢中的相变模型。使用这种方法表明,当考虑立方产物相时,在γ相中留下一个密排面且该平面内的一个密排方向不旋转的转变应变,恰好就是产生NW和KS ORs的应变。此外,还概述了如何通过选择不同的未旋转平面和方向对,推导出其他常见的ORs,如皮茨模型和格雷宁格-特罗亚诺模型。我们方法的优点之一是,对于产物体心四方α'相不同的四方度r比值,它能自然地推广NW、KS和其他ORs。这些广义的ORs预测,随着四方度增加,转变织构会变尖锐,因此在定性上与不同合金浓度钢的实验结果一致。