Suppr超能文献

过渡路径时间分布、隧穿时间、摩擦力与不确定性

Transition Path Time Distribution, Tunneling Times, Friction, and Uncertainty.

作者信息

Pollak Eli

机构信息

Chemical Physics Department, Weizmann Institute of Science, 76100 Rehovoth, Israel.

出版信息

Phys Rev Lett. 2017 Feb 17;118(7):070401. doi: 10.1103/PhysRevLett.118.070401. Epub 2017 Feb 15.

Abstract

A quantum mechanical transition path time probability distribution is formulated and its properties are studied using a parabolic barrier potential model. The average transit time is well defined and readily calculated. It is smaller than the analogous classical mechanical average transit time, vanishing at the crossover temperature. It provides a direct route for determining tunneling times. The average time may be also used to define a coarse grained momentum of the system for the passage from one side of the barrier to the other. The product of the uncertainty in this coarse grained momentum with the uncertainty in the location of the particle is shown under certain conditions to be smaller than the ℏ/2 formal uncertainty limit. The model is generalized to include friction in the form of a bilinear interaction with a harmonic bath. Using an Ohmic friction model one finds that increasing the friction, increases the transition time. Only moderate values of the reduced friction coefficient are needed for the quantum transition time and coarse grained uncertainty to approach the classical limit which is smaller than ℏ/2 when the friction is not too small. These results show how one obtains classical dynamics from a pure quantum system without invoking any further assumptions, approximations, or postulates.

摘要

提出了一种量子力学跃迁路径时间概率分布,并使用抛物线势垒模型研究了其性质。平均穿越时间定义明确且易于计算。它比类似的经典力学平均穿越时间小,在交叉温度下消失。它为确定隧穿时间提供了一条直接途径。平均时间还可用于定义系统从势垒一侧穿越到另一侧时的粗粒化动量。在某些条件下,这种粗粒化动量的不确定性与粒子位置的不确定性的乘积小于ħ/2的形式不确定性极限。该模型被推广到包括与谐振子浴的双线性相互作用形式的摩擦。使用欧姆摩擦模型发现,增加摩擦会增加跃迁时间。当摩擦不太小时,仅需适度的约化摩擦系数值,量子跃迁时间和粗粒化不确定性就能接近小于ħ/2的经典极限。这些结果展示了如何在不引入任何进一步假设、近似或假设的情况下,从纯量子系统中获得经典动力学。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验