Galli Giancarlo, Martinelli Elisa
Dipartimento di Chimica e Chimica Industriale and UdR Pisa INSTM, Università di Pisa, 56124, Pisa, Italy.
Macromol Rapid Commun. 2017 Apr;38(8). doi: 10.1002/marc.201600704. Epub 2017 Mar 7.
A range of amphiphilic polymers with diverse macromolecular architectures has been developed and incorporated into films and coatings with potential for marine antibiofouling applications, without resorting to addition of currently used biocidal, toxic agents. Novel "green" chemical technologies employ different building blocks to endow the polymer film with surface activity, functionality, structure, and reconstruction according to the outer environment as a result of a tailored amphiphilic character of the polymer platform. We emphasise how these features can interplay and add synergistically to affect antifouling and fouling-release against common, widespread marine micro- and macro-fouling organisms.
一系列具有不同大分子结构的两亲性聚合物已被开发出来,并被纳入具有海洋防污应用潜力的薄膜和涂层中,而无需添加目前使用的杀生、有毒剂。新型“绿色”化学技术采用不同的构建模块,由于聚合物平台具有定制的两亲性特征,可根据外部环境赋予聚合物薄膜表面活性、功能性、结构和重构能力。我们强调这些特性如何相互作用并协同发挥作用,以影响对常见、广泛存在的海洋微污损和宏污损生物的防污和污损释放效果。