Faculty of Mechanical Engineering, University of Maribor, Smetanova 17, SI-2000 Maribor, Slovenia.
Faculty of Chemistry and Chemical Engineering, University of Ljubljana, Večna Pot, 113 SI-1000 Ljubljana, Slovenia.
Carbohydr Polym. 2017 May 1;163:92-100. doi: 10.1016/j.carbpol.2017.01.060. Epub 2017 Jan 20.
This study introduces a novel green in-situ procedure for introduction of silver nanoparticles (Ag NPs) on and into cellulose fibres in a three-stage process. First-stage of the process includes the activation of cellulose fibres in alkaline solution, followed by reduction of silver nitrate to Ag NPs in the second stage, while the last stage of process involves washing and neutralization of fibres. Efficiency of the method towards incorporation of silver particles into the fibres' internal structure was characterized; the coatings' morphology and determination of spatial presence of Ag particles were imagining by the scanning electron microscopy and accompanying energy dispersive x-ray spectroscopy analysis; prepared fibres have superior durability of particles' coating against washing and excellent antimicrobial activity even after 20 washing cycles. Additionally, the water retention of silver treated fibres was improved, while the mechanical properties were not significantly impaired.
本研究提出了一种新颖的绿色原位法,可分三个阶段将银纳米粒子 (Ag NPs) 引入并固定在纤维素纤维上。该方法的第一阶段包括在碱性溶液中对纤维素纤维进行活化,第二阶段还原硝酸银为 Ag NPs,最后阶段则为纤维的洗涤和中和。该方法对将银颗粒引入纤维内部结构的效率进行了表征;通过扫描电子显微镜和伴随的能谱分析对涂层的形态和 Ag 颗粒的空间存在进行了成像;制备的纤维具有优异的耐久性,即使经过 20 次洗涤循环,其颗粒涂层的抗菌活性仍保持不变。此外,经银处理的纤维的保水能力得到提高,而机械性能则没有明显受损。