Perestrelo R, Silva C, Silva P, Câmara J S
CQM - Centro de Química da Madeira, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal.
CQM - Centro de Química da Madeira, Universidade da Madeira, Campus da Penteada, 9020-105 Funchal, Portugal.
Food Chem. 2017 Jul 15;227:111-121. doi: 10.1016/j.foodchem.2017.01.090. Epub 2017 Jan 18.
The global volatile profile of commercial virgin olive oils and flavoured olive oils with aromatic/medicinal plants, was established using liquid-liquid microextraction (LLME) and headspace solid-phase microextraction (HS-SPME) combined with gas chromatography-quadrupole mass spectrometry (GC-qMS). More than 60 volatile organic compounds (VOCs belonging to different groups were identified using both methods. Olive oils volatile profile was slightly influenced by maceration process, which occurred at room temperature (20±2°C) for 15days. The predominant differences were observed in terpenoids group, since some of them were only identified in the flavoured olive oils, while others showed an increase with the maceration process. VOCs mass transfer from plants to olive oils could explain the observed results. Principal components analysis (PCA) applied to LLME/GC-qMS data allowed to distinguish the olive oils. The flavoured oils would increase the use of olive oil among consumers as consequence of the improvement of its aromatic profile and healthy properties.
采用液-液微萃取(LLME)和顶空固相微萃取(HS-SPME)结合气相色谱-四极杆质谱(GC-qMS)技术,建立了市售初榨橄榄油以及添加芳香/药用植物的调味橄榄油的全球挥发性成分谱。两种方法共鉴定出60多种属于不同类别的挥发性有机化合物(VOCs)。橄榄油的挥发性成分谱受浸渍过程的影响较小,浸渍在室温(20±2°C)下进行15天。在萜类化合物组中观察到了主要差异,因为其中一些仅在调味橄榄油中被鉴定出来,而另一些则随着浸渍过程而增加。VOCs从植物到橄榄油的传质过程可以解释观察到的结果。对LLME/GC-qMS数据进行主成分分析(PCA)可以区分橄榄油。由于其香气特征和健康特性的改善,调味油将增加消费者对橄榄油的使用。