Song Li-Cheng, Yang Xi-Yue, Cao Meng, Gao Xiu-Yun, Liu Bei-Bei, Zhu Liang, Jiang Feng
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China.
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
Chem Commun (Camb). 2017 Mar 30;53(27):3818-3821. doi: 10.1039/c7cc00149e.
The structural and functional modeling of the active site of [NiFe]-hydrogenases has been proved to be challenging to a great extent. Herein, we report the synthesis, structures, and some properties of the NiFe-based dicarbonyl, terminal hydride, and μ-hydroxo models for the active site of [NiFe]-hydrogenases.
[NiFe]氢化酶活性位点的结构和功能建模在很大程度上已被证明具有挑战性。在此，我们报道了用于[NiFe]氢化酶活性位点的镍铁基二羰基、端基氢化物和μ-羟基模型的合成、结构及一些性质。
