Crystal structure of a Co coordination polymer: -poly[[μ-aqua-bis-(μ-2-methyl-propano-ato)-κ:';κ:-cobalt(II)] monohydrate].

In the title cobalt(II) coordination polymer with isobutyrate ligands, {[Co{CH(CH)CO}(HO)]·HO} , the Co ion is hexa-coordinated in a slightly distorted octa-hedral coordination environment defined by two O atoms from two bridging water mol-ecules and four O atoms from four bridging carboxyl-ate ligands. The carboxyl-ates adopt two different coordination modes, μ-(κ:') and μ-(κ:), forming a one-dimensional polymeric chain extending along [010]. The intra-chain cobalt⋯cobalt separation is 3.2029 (2) Å. The polymeric chains are linked by hydrogen bonds involving the water mol-ecules of solvation, giving a two-dimensional network structure lying parallel to (100).