Faizi Md Serajul Haque, Ali Akram, Potaskalov Vadim A
Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36, Al-Khod 123, Muscat, Sultanate of Oman.
Department of Chemistry, Indian Institute of Technology, Kanpur 208 016 UP, India.
Acta Crystallogr E Crystallogr Commun. 2017 Feb 28;73(Pt 3):459-462. doi: 10.1107/S205698901700281X. eCollection 2017 Mar 1.
In the title mononuclear complex, [Ru(CHO)(CHN)], the Ru ion has a distorted octa-hedral coordination environment defined by two N atoms of the chelating 2,2'-bi-pyridine ligand and four O atoms from two 3,5-di--butyl-benzo-quinone ligands. In the crystal, the complex mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonds and π-π stacking inter-actions between the 2,2'-bi-pyridine ligands [centroid-centroid distance = 3.538 (3) Å], resulting in a layer structure extending parallel to the plane.
在标题单核配合物[Ru(CHO)(CHN)]中，Ru离子具有扭曲的八面体配位环境，由螯合的2,2'-联吡啶配体的两个N原子和来自两个3,5-二叔丁基苯醌配体的四个O原子界定。在晶体中，配合物分子通过分子间C-H⋯O氢键和2,2'-联吡啶配体之间的π-π堆积相互作用相连[质心-质心距离 = 3.538 (3) Å]，形成平行于平面延伸的层状结构。
