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使用聚苯胺衍生聚合物作为模板实现银纳米带的尺寸可调合成。

Size-tunable Synthesis of Silver Nanobelts Using a Polyaniline Derived Polymer as a Template.

机构信息

Department of Bio &Nano Chemistry, Kookmin University, 861-1, Jeongneung-dong, Seongbuk-gu, Seoul, Republic of Korea.

出版信息

Sci Rep. 2017 Mar 20;7:44796. doi: 10.1038/srep44796.

DOI:10.1038/srep44796
PMID:28317940
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5357892/
Abstract

Silver nanobelts (AgNBs) have attracted a great interest due to their excellent electrical conductivity and mechanical strength, leading a facile synthesis of these AgNBs in great demand. In here, we are reporting a simple, aqueous phase, size tunable synthesis of smooth surfaced 1D-silver nanobelts using a Polyaniline (PANi) derived polymer at room temperature. The specifically designed PANi polymer, comprising a pendant carboxyl group in the chain, acted as both a reducing agent and template. The resulting Ag nanobelts have more than 10 μm of length, mean width values ranging from 41.1 (11.5) nm to 118.5 (8.8) nm and a mean thickness value of 36.7 (12.5) nm. The UV-Visible spectrum of the AgNBs has shown two Surface Plasmon Resonance peaks at 352 nm and 383 nm.

摘要

银纳米带(AgNBs)因其优异的导电性和机械强度而备受关注,因此人们迫切需要一种简便的方法来合成这些 AgNBs。在这里,我们报道了一种简单的、在水溶液中、可调控尺寸的方法,即在室温下使用聚苯胺(PANI)衍生聚合物合成具有光滑表面的一维银纳米带。所设计的 PANi 聚合物在链上带有一个侧挂的羧基基团,同时起到还原剂和模板的作用。所得的 Ag 纳米带长度超过 10μm,平均宽度值范围从 41.1(11.5)nm 到 118.5(8.8)nm,平均厚度值为 36.7(12.5)nm。AgNBs 的紫外-可见光谱在 352nm 和 383nm 处显示出两个表面等离子体共振峰。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/f219ecbb9d2f/srep44796-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/ce5dabb21ce0/srep44796-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/3633de8c80fb/srep44796-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/d399eb0bd93b/srep44796-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/9c12d4a2916b/srep44796-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/f219ecbb9d2f/srep44796-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/ce5dabb21ce0/srep44796-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/3633de8c80fb/srep44796-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/d399eb0bd93b/srep44796-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/9c12d4a2916b/srep44796-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a50b/5357892/f219ecbb9d2f/srep44796-f5.jpg

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Growth and optical properties of silver nanostructures obtained on connected anodic aluminum oxide templates.在连接的阳极氧化铝模板上获得的银纳米结构的生长和光学性质。
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Ag nanobelts: synthesis, morphological evolution, and their use as electrocatalysts for oxygen reduction.
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Chemistry. 2012 May 7;18(19):6049-54. doi: 10.1002/chem.201103926. Epub 2012 Mar 27.
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A systematic study of the synthesis of silver nanoplates: is citrate a "magic" reagent?银纳米片的合成研究:柠檬酸盐是一种“神奇”试剂吗?
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