Greño Maider, Mena Miguel, Pérez-Redondo Adrián, Yélamos Carlos
Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá, 28805 Alcalá de Henares-Madrid, Spain.
Dalton Trans. 2017 Apr 19;46(16):5138-5142. doi: 10.1039/c7dt00857k.
Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η-CMe)(NMe)Cl] (n = 3, 1) with amine-borane adducts NHRBH (R = Me, HtBu). The reactions involve the formation of amidoborane ligands with ZrH-B interactions which readily undergo β-hydride elimination to give hydride functions.
单核、双核和三核氢化锆物种已通过用胺硼烷加合物NHRBH（R = Me，HtBu）处理酰胺配合物[Zr(η-CMe)(NMe)Cl]（n = 3，1）而分离出来。这些反应涉及形成具有ZrH-B相互作用的酰胺硼烷配体，该配体容易发生β-氢消除反应以生成氢化物官能团。
