用于未活化烯烃亲核试剂阳极环加成反应的熵电解质。
Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles.
作者信息
Imada Yasushi, Yamaguchi Yusuke, Shida Naoki, Okada Yohei, Chiba Kazuhiro
机构信息
Department of Applied Biological Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan.
Department of Chemical Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan.
出版信息
Chem Commun (Camb). 2017 Apr 4;53(28):3960-3963. doi: 10.1039/c7cc00664k.
Unactivated alkenes were previously found to be effective carbon nucleophiles for anodic cycloadditions in lithium perchlorate/nitromethane electrolyte solution. Herein, Li NMR analysis and calorimetric studies clearly illustrate that the entropic effect is essential for these anodic cycloadditions, which has led to the successful screening of novel effective electrolytes.
先前发现未活化的烯烃在高氯酸锂/硝基甲烷电解质溶液中是用于阳极环加成反应的有效碳亲核试剂。在此，锂核磁共振分析和量热研究清楚地表明，熵效应对于这些阳极环加成反应至关重要，这已导致成功筛选出新型有效电解质。
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