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超疏水 BN 调控海绵,采用绿色简便方法制备,具有优异的吸水性。

Superhydrophobic hBN-Regulated Sponges with Excellent Absorbency Fabricated Using a Green and Facile Method.

机构信息

School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, P R China.

School of Naval Architecture and Ocean Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, P R China.

出版信息

Sci Rep. 2017 Mar 23;7:45065. doi: 10.1038/srep45065.

Abstract

The world faces severe environmental, human and ecological problems when major oil spills and organic discharges are released into the environment. And so it is imperative to develop tools and high performance innovative materials that can efficiently absorb these organic discharges. Furthermore, green, facile methods to produce these advanced materials are also needed. In this paper, we demonstrate a novel porous supersponge based on melamine coated with hBN. This superhydrophobic sponge (with a contact angle >150°) exhibits excellent absorption performance for oils and organic solvents, including good selectivity, high capacity (up to 175 g·g) and extraordinary recyclability (less than 20% decline after 30 cycles of absorption/squeezing). The synthetic procedure required only ultrasonication and immersion of the sponge in aqueous hBN solution, being a green, cost-effective and scalable production methodology. By virtue of the straightforward and cost-effective fabrication method, along with the excellent absorption performance, hBN-decorated sponges have great promise for real world practical application in the field of oil spills and organic leakage cleanup.

摘要

当大量石油泄漏和有机排放物进入环境时,世界将面临严重的环境、人类和生态问题。因此,开发能够有效吸收这些有机排放物的工具和高性能创新材料势在必行。此外,还需要绿色、简便的方法来生产这些先进材料。在本文中,我们展示了一种基于三聚氰胺涂覆 hBN 的新型多孔超级海绵。这种超疏水海绵(接触角>150°)对油和有机溶剂表现出优异的吸收性能,具有良好的选择性、高容量(高达 175 g·g)和非凡的可回收性(在 30 次吸收/挤压循环后下降不到 20%)。该合成过程仅需超声处理和将海绵浸入水性 hBN 溶液中,是一种绿色、经济高效且可扩展的生产方法。凭借简单且经济高效的制造方法以及优异的吸收性能,hBN 修饰的海绵在处理石油泄漏和有机泄漏方面具有广阔的实际应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7332/5362905/bb86d3eb3638/srep45065-f1.jpg

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