Sun Lihua, He Ning, Yu Tianmin, Duan Xi, Feng Cuimin, Zhang Yajun
Key Laboratory of Urban Stormwater System & Water Environment, Beijing University of Civil Engineering and Architecture, Beijing 100044, China E-mail:
School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China.
Water Sci Technol. 2017 Mar;75(5-6):1485-1493. doi: 10.2166/wst.2017.016.
This paper focused on the effects of powdered activated carbon (PAC) dosage on ultrafiltration (UF) membrane flux caused by natural organic matter (NOM). Three model foulants, humic acid (HA), bovine serum albumin (BSA) and sodium alginate (SA), were adopted to represent different NOM fractions in secondary effluent treated by the combined process of PAC-UF. Moreover, the membrane fouling resistance and fouling mechanism were also analyzed. The results indicated that the best PAC dosage for the membrane flux variation was 20 mg/L for HA and SA, and 10 mg/L for BSA. SA caused the most serious membrane fouling, which was mainly reversible fouling. The membrane fouling caused by HA and BSA was mainly irreversible membrane fouling. The membrane fouling caused by organics happened mainly at the initial stage of filtration. Because the filter cake layer formed by a moderate amount of PAC could intercept organics, the membrane fouling, especially the irreversible fouling, could be reduced.
本文聚焦于粉末活性炭(PAC)投加量对天然有机物(NOM)导致的超滤(UF)膜通量的影响。采用腐殖酸(HA)、牛血清白蛋白(BSA)和海藻酸钠(SA)这三种模型污染物来代表经PAC-UF组合工艺处理的二级出水中不同的NOM组分。此外,还分析了膜污染阻力和污染机理。结果表明,对于HA和SA,使膜通量变化的最佳PAC投加量为20 mg/L,对于BSA为10 mg/L。SA导致的膜污染最严重,主要为可逆污染。由HA和BSA导致的膜污染主要为不可逆膜污染。有机物导致的膜污染主要发生在过滤初期。由于适量PAC形成的滤饼层能够截留有机物,因此可以减少膜污染,尤其是不可逆污染。