Encapsulation induced aggregation: a self-assembly strategy for weakly pi-stacking chromophores.
作者信息
Sao Soumik, Mukherjee Ishita, De Priyadarsi, Chaudhuri Debangshu
机构信息
Department of Chemical Sciences and Centre for Advanced Functional Materials (CAFM), Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur 741246, India.
出版信息
Chem Commun (Camb). 2017 Apr 4;53(28):3994-3997. doi: 10.1039/c7cc00554g.
PMID:28337495
Abstract
Molecular assembly of weakly pi-stacking core-substituted naphthalene diimides (cNDIs) requires the participation of strong side-group interactions. Spatial confinement within a micellar core leads to locally elevated concentrations and reduced entropy that drives a rapid aggregation, often followed by a slower aggregate reorganization. Fast aggregation kinetics leads to self-sorting of aggregates.
摘要
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