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Enhanced single-ion magnetic and ferroelectric properties of mononuclear Dy(iii) enantiomeric pairs through the coordination role of chiral ligands.

作者信息

Li Xi-Li, Hu Ming, Yin Zhigang, Zhu Cancan, Liu Cai-Ming, Xiao Hong-Ping, Fang Shaoming

机构信息

Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou, Henan 450002, P. R. China.

Bejing National Laboratory for Molecular Sciences, Institution of Chemistry, Chinese Academy of Sciences, Bejing 100190, P. R. China.

出版信息

Chem Commun (Camb). 2017 Apr 4;53(28):3998-4001. doi: 10.1039/c7cc01042g.

DOI:10.1039/c7cc01042g
PMID:28338140
Abstract

The structures and properties of two mononuclear Dy(iii) enantiomeric pairs were dramatically controlled by crystallization temperature; the enantiomeric pair with coordinated chiral N,N'-donor ligands exhibits enhanced single-ion magnetic, ferroelectric and chiroptical properties with respect to the other one with protonated chiral N,N'-donor ligands.

摘要

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