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Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines.

作者信息

Ray Ritwika, Chandra Shubhadeep, Yadav Vishal, Mondal Prasenjit, Maiti Debabrata, Lahiri Goutam Kumar

机构信息

Department of Chemistry, Indian Institute of Technology, Bombay, Powai, Mumbai-400076, India.

出版信息

Chem Commun (Camb). 2017 Apr 4;53(28):4006-4009. doi: 10.1039/c6cc10200j.

Abstract

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.

摘要

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