聚（蒽醌基硫醚）/石墨烯片复合材料作为电化学电容器电极材料的电化学性能

Electrochemical Properties of Poly(Anthraquinonyl Sulfide)/Graphene Sheets Composites as Electrode Materials for Electrochemical Capacitors.

作者信息

Lee Wonkyun, Suzuki Shinya, Miyayama Masaru

机构信息

School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

CREST, Japan Science and Technology Agency, 4-8-1 Honcho, Kawaguchi, Saitama 332-0012, Japan.

出版信息

Nanomaterials (Basel). 2014 Jul 30;4(3):599-611. doi: 10.3390/nano4030599.

Poly(anthraquinonyl sulfide) (PAQS)/graphene sheets (GSs) composite was synthesized through polymerization to evaluate its performance as an electrode material for electrochemical capacitors. PAQS was successfully synthesized in the presence of GSs with uniform distribution. PAQS/GSs showed a pair of reversible redox peaks at around 0 V ( Ag/AgCl). The specific capacitance of PAQS/GSs was 349 F·g (86 mAh·g) at a current density of 500 mA·g, and a capacitance of 305 F·g was maintained even at a high current density of 5000 mA·g. The polymerization of PAQS with GSs facilitated their interaction and enabled faster charge transfer and redox reaction, resulting in enhanced electrode properties.