Scharlack Nayara K, Aracava Keila K, Rodrigues Christianne Ec
Separation Engineering Laboratory (LES), Department of Food Engineering, University of Sao Paulo (USP), Pirassununga, Sao Paulo, Brazil.
J Sci Food Agric. 2017 Oct;97(13):4612-4620. doi: 10.1002/jsfa.8331. Epub 2017 May 2.
The present study aimed to evaluate the replacement of hexane by alcoholic solvents in oil extraction from sunflower seed press cake. The use of ethanol and isopropanol has important advantages, including low toxicity and good operational safety. Thus, in the present study, solid-liquid extractions were performed in a single stage from 60 to 90 °C and in consecutive extractions in three stages at 90 °C.
Solvent hydration negatively affected the extraction of oil but favored the extraction of chlorogenic acids (CAs), especially when ethanol was used. Regarding oxidative stability, the oils extracted using ethanol presented long induction times, which could be related to the high levels of not only CAs and tocopherols, but also phospholipids.
Alcoholic solvents can be used for extraction to produce sunflower seed oil containing minor compounds that give it greater oxidative stability. In addition, the results obtained using hydrous ethanol showed that this solvent can yield defatted sunflower seed meal with a low content of CAs, enabling future use of the protein fraction. © 2017 Society of Chemical Industry.
本研究旨在评估在从葵花籽压榨饼中提取油脂时用醇类溶剂替代己烷的情况。乙醇和异丙醇的使用具有重要优势,包括低毒性和良好的操作安全性。因此,在本研究中,进行了单阶段60至90°C的固液萃取以及在90°C下分三个阶段的连续萃取。
溶剂水合作用对油脂提取有负面影响,但有利于绿原酸(CAs)的提取,尤其是使用乙醇时。关于氧化稳定性,用乙醇提取的油脂具有较长的诱导期,这可能与高水平的CAs、生育酚以及磷脂有关。
醇类溶剂可用于提取以生产含有赋予其更高氧化稳定性的次要化合物的葵花籽油。此外,使用含水乙醇获得的结果表明,这种溶剂可生产出CAs含量低的脱脂葵花籽粕,从而使蛋白质部分能够在未来得到利用。©2017化学工业协会。