铕（Ⅲ）（六氟乙酰丙酮）与平面手性磷（Ⅲ）配体（二苯基膦基萘）形成的配合物：圆偏振发光的溶剂敏感信号反转
Complexes of Eu(iii)(hfa) with a planar chiral P(iii) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence.
作者信息
Kono Yuki, Hara Nobuyuki, Shizuma Motohiro, Fujiki Michiya, Imai Yoshitane
机构信息
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
出版信息
Dalton Trans. 2017 Apr 19;46(16):5170-5174. doi: 10.1039/c7dt00741h.
PMID:28350022
Abstract
Complexes of Eu(iii)(hfa) with a C-symmetric planar P(iii) ligand exhibited intense circularly polarised luminescence (CPL) due to D → F and D → F transitions, with the signs and shapes of CPL signals depending on the choice of solvent (acetone or chloroform).
摘要
铕（III）（六氟乙酰丙酮）与一种具有C对称性的平面型磷（III）配体形成的配合物，由于D→F和D→F跃迁而表现出强烈的圆偏振发光（CPL），CPL信号的符号和形状取决于溶剂（丙酮或氯仿）的选择。
Zotero 插件