Vela Sonia, Berrocal José Augusto, Atienza Carmen, Meijer E W, Martín Nazario
Departamento Química Orgánica, Facultad C. C. Químicas, Universidad Complutense de Madrid, Av. Complutense s/n, 28040 Madrid, Spain and Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.
Institute for Complex Molecular Systems, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.
Chem Commun (Camb). 2017 Apr 6;53(29):4084-4087. doi: 10.1039/c7cc01670k.
Mesoscopic super-helices with preferred helicity have been serendipitously formed from the self-assembly of electroactive extended core discotic molecules. The investigation at dilute concentrations reveals intramolecular hydrogen-bonding and π-π stacking interactions as the driving force of the chiral self-assembly at different length scales.
具有优先螺旋性的介观超螺旋已由电活性扩展核盘状分子的自组装意外形成。在稀溶液浓度下的研究表明，分子内氢键和π-π堆积相互作用是不同长度尺度下手性自组装的驱动力。
